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Olen nõus

Viktor Palm

https://etis.ee/CV/Viktor_Palm/est
17.09.1926
737 5262
viktor.palm@ut.ee

Teenistuskäik

Töökohad ja ametid
1952 - 1964 TÜ, org. keemia kat., v-õpet, dotsent
1964-1992 -samas, dots, prof. kat juhat
1992-2005 - TÜ Keemilise Füüsika Instituurt, emer.-professor, teadur
01.07.2006–31.07.2007   
Tartu Ülikool, Füüsika-keemiateaduskond, Keemilise füüsika instituut, erakorraline teadur (0,25)
 
 
Haridustee
Kõrgem, Leningradi Riikliku ÜLikooli Keemiateaduskond, Keemik, 1952
 
 
Teadusorganisatsiooniline ja -administratiivne tegevus
-

Kvalifikatsioon

Teaduskraadid
Viktor Palm, doktorikraad, 1966, (juh) -, Quantitative Investigations on Organic Reactivity, Instit. of Elementorg. Chem. Ac. Sci. USSR.
 
 
Teaduspreemiad ja tunnustused
1997, Viktor Palm, Riigi teaduspreemia
0, Viktor Palm, EV TA tegevliige (1978), Eesti riiklik elutöö preemia (1996), Eesti TA ja TÜ medalid, Valgetähe IV kl. orden.
 
 
Lisainfo
Keemiadoktor
NSVL TA Elementorgaaniliste Ühendite Inst., 1966

Juhendanud 15 kadidaadi väitekirja

Juhendatud väitekirjad

Publikatsioonid

Klass
Aasta
Publikatsioon
 
1.2.
2006
Palm, V.; Palm, N.; Tenno, T. (2006). Computerized database and software for retrieval, processing and prognosis of rate and equilibrium constants of chemical reactions. Proceedings of the Estonian Academy of Sciences. Chemistry, 55 (1), 3−13.
1.1.
2004
Palm, V.; Palm, N.; Tenno, T. (2004). Modification of data processing and interpretation of results related to the use of multiparameter correlation analysis: introduction of additional characteristics and criterias. Part 1 - Application to the treatment of solvent effects. Journal of Physical Organic Chemistry, 17 (10), 876−889.
5.1.
2004
Palm, V.; Kiho, J.; Jalas, A.; Tenno, T.; Palm, N. (2004). Computerized Database on Chemical Reactivity (Rate and Equilibrium Constants) and Concerted Software for Retrieval, Processing, and Prognosis of Data. International Conference on Education and Information Systems: Technologies and Applications, vol, 2, Proceedings: International Conference on Education and Information Systems (EISTA '04); Orlando, USA; 21-25 July, 2004. Orlando, USA, 190−195.
5.2.
2004
Palm, V.; Tenno, T.; Palm, N. (2004). Averaged Values and the Problem of Generality for Substituent Constants. The Tenth International Conference on Correlation Analyis in Chemistry (CAIC, X): The Tenth International Conference on Correlation Analyis in Chemistry; Busan, Korea; 2004.
1.1.
2001
Palm, N.; Palm, V. (2001). Verification of the Modified Approach to Solvation Effects on The Basis of Extended Data Set: III. Results of Statistical Data Treatment for Particular Processes. Russian Journal of Organic Chemistry, 37 (7), 935−939.
1.2.
2001
Jalas, A.; Palm, V.; Tenno, T. (2001). A Computerized Storage and Retrieval System of pKa Values of Hydrogen Acids. Proceedings of the Estonian Academy of Sciences. Chemistry, 50 (3), 186−192.
3.1.
2001
Palm, V. (2001). Some fundamental criteria of the scientific method and the internal structure of science. In: Vihalemm, R. (Ed.). Estonian studies in the history and philosophy of science (91−110). . Dordrecht/Boston/London: Kluwer Academic Publishers. (Boston studies in the philosophy of science; 219).
3.3.
2001
Palm, V.; Jalas, A.; Tenno, T. (2001). PKa Database. Dissociation of Hydrogen Acids (http:/mega.chem.ut.ee/tktool/teadus/pkdb). 1.
1.1.
2000
Palm, N.; Palm, V. (2000). Verification of modified approach to solvation effects based on extended set of data series II: Procedure and verification results of averaged statistical significance of solvent constants scales. Russian Journal of Organic Chemistry, 36 (8), 1075−1104.
1.2.
1997
Palm, V.; Palm, N. (1997). Check of a Modified Approach to Solvent Effects by Processing of an Extended Set of Solvent-Dependent Data Series. 1. Test of an Earlier Defined Set of Nine Solvent Parameters. Organic Reactivity, 31 (104), 141−158.
1.3.
1997
Palm, V.; Jalas, A.; Kiho, J.; Tenno, T. (1997). A Computerised System for the Storage, Processing and Prognostication of Data with Orientation Toward the Use of Correlation Equations. Organic Reactivity, 31 (1), 111−133.
1.3.
1997
Jalas, A.; Kiho, J.; Palm, V.; Tenno, T. (1997). Data Structure and Menu-based Access of the Rate and Equilibrium Constants of Heterolytic Organic Reactions Database. Organic Reactivity, 31 (1), 135−140.
1.2.
1996
Nummert, V.; Piirsalu, M.; Palm, V. (1996). Kinetic Study of Hydrolysis of Benzoates. XIX. Influence of Temperature on Ortho Effect for Water Solution. Isokinetic Dependence in the Case of Additional Ortho Induction Effect. Organic Reactivity, 30, 85−94.
1.1.
1993
Hiob, R.; Palm, V. (1993). Structural and Temperature Effects in the Gas Phase Hydrogen Abstraction Reactions from Compounds with General Structure R-H. 2. Abstraction by Variable Free Radicals. Organic Reactivity, 28, 119−124.
1.1.
1993
Palm, V.; Palm, N. (1993). On the Total Number and List of Parameter Scales Significant for General Quantitative Description of Solvent Effects. Organic Reactivity, 28, 125−152.
1.1.
1993
Hiob, R.; Palm, V. (1993). Structural and Temperature Effects in the Gas Phase Hydrogen Abstraction Reactions from Compounds with General Structure R-H. Abstraction by Hydrogen Atom. Organic Reactivity, 28, 110−118.
1.2.
1993
Nummert, V.; Piirsalu, M.; Palm, V. (1993). Kinetic Study of Alkaline Hydrolysis of Substituted Phenyl Tosylates. XXI. Influence of Solvent on Ortho Effect. Organic Reactivity, 28, 82−87.
1.2.
1993
Hiob, R.; Palm, V. (1993). Structural and Temperature Effects in the Gas Phase Hydrogen Abstraction Reactions from Compounds with General Structure R-H. 1. Abstraction by Hydrogen Atom. Organic Reactivity, 28, 110−118.
1.1.
1990
Palm, V. (1990). Computer-managed automatic data-retrieval and prognosis system for rate and equilibrium-constants of organic-reactions. Journal of Chemical Information and Computer Sciences, 30 (4), 409−412.
1.1.
1990
Nummert, VM.; Piirsalu, MV.; Palm, VA. (1990). Kinetic-study of alkaline-hydrolysis of substituted phenyl tosylates. 18. Results of kinetic measurements of o-substituted tosylates in 80-percent aqueous dimethylsulfoxide. Organic Reactivity, 27, 99−127.
1.1.
1987
Tuulmets, A.; Horak, M.; Hansen, E.; Palm, V. (1987). Some structure-reactivity relationships for alkylbromides in the grignard reaction. Organic Reactivity, 24 (4), 412−424.
1.1.
1986
Palm, V.; Hiob, R.J. (1986). Quantitative Statistical Interpretation of Kinetic Data in the Gas-Phase Homolysis .8. Program for Automatic Computational Estimation of Rate Constants of Gas-Phase Homolysis and Heats of Formation of Covalent Compounds. Organic Reactivity, 23 (4), 412−439.
1.1.
1986
Palm, VA.; Hiob, RJ. (1986). Quantitative statistical interpretation of kinetic data in the gas-phase homolysis. 8. Program for automatic computational estimation of rate constants of gas-phase homolysis and heats of formation of covalent compounds. Organic Reactivity, 23 (4), 412−439.
1.1.
1986
Sild, VA.; Palm, VA. (1986). Realization of the general algorithm of the solution of direct problems for homogeneous equilibrium-kinetic mechanistic schemes. Organic Reactivity, 23 (4), 482−506.
1.1.
1985
Koppel, IA.; Molder, UH.; Palm, VA. (1985). Abinitio SCF LCAO MO calculations of molecules. 4. Proton affinities - comparison with experiment. Organic Reactivity, 22 (1), 3−45.
1.1.
1985
Palm, N.; Palm, V. (1985). Determination of the kinetic equilibrium parameters of the reaction of triphenylaluminum with benzophenone. Organic Reactivity, 22 (2), 131−141.
1.1.
1985
Matveev, AA.; Piskunova, ZP.; Palm, VA. (1985). Factors effecting rate of menshutkin reaction. 1. Effect of amine structure. Organic Reactivity, 22 (1), 110−118.
1.1.
1985
Matveev, AA.; Piskunova, ZP.; Palm, VA. (1985). Factors effecting the rate of menshutkin reaction. 2. Interdependence of reagents structure effects. Organic Reactivity, 22 (2), 153−161.
1.1.
1985
Nummert, V.; Eek, M.; Palm, V. (1985). Kinetic-study of alkaline-hydrolysis of substituted phenyl tosylates. 14. Discussion of results of kinetic measurements in 80-percent aqueous dimethylsulfoxide. Organic Reactivity, 22 (3), 263−294.
1.1.
1984
Leinbock, RA.; Palm, VA. (1984). Nonlinear parametrization of equations for atomic spectral terms. 2. Data-processing applying the minimization of relative standard-deviation in the equation with a reduced number of parameters. Organic Reactivity, 21 (2), 127−143.
1.1.
1984
Juriado, TJ.; Palm, VA. (1984). Program package for computer-storage and automatic search of correlation equations and for calculation of rate and equilibrium-constants. 1. Digital coding system of equations of chemical-reactions. Organic Reactivity, 21 (3), 255−284.
1.1.
1983
Leinbock, RA.; Palm, VA. (1983). Nonlinear parametrization of equations for atomic spectral terms. 1. Specification of general character of dependence on orbital-orbital shielding constants. Organic Reactivity, 20 (3), 373−396.
1.1.
1983
Hiob, R.; Palm, V. (1983). Quantitative statistical interpretation of kinetic data in the gas-phase homolysis. 3. Calculation of conventional formation enthalpies of free-radicals in the approximation of constant effective mean-value of log a0=14.64. Organic Reactivity, 20 (2), 151−202.
1.1.
1983
Hiob, R.; Palm, V. (1983). Quantitative statistical interpretation of kinetic data in the gas-phase homolysis. 4. Calculation of conventional formation enthalpies of free-radicals based on experimental activation-energies, isokinetic and isoentropic models. Organic Reactivity, 20 (2), 257−274.
1.1.
1983
Palm, VA.; Hiob, RJ. (1983). Quantitative statistical interpretation of kinetic data in the gas-phase homolysis. 5. Correlation of substituent effects on conventional formation enthalpies of substituted methyl radicals proceeding from isoentropic and isokinetic models. Organic Reactivity, 20 (3), 321−354.
1.1.
1983
Hiob, RJ.; Palm, VA. (1983). Quantitative statistical interpretation of kinetic data in the gas-phase homolysis. 6. Attempt of simultaneous estimation of entropy and enthalpy contributions in free-energy of activation. Organic Reactivity, 20 (3), 405−443.
1.1.
1983
Uri, A.; Tuulmets, A.; Palm, V. (1983). Trans-esterification of esters of carboxylic-acids by titanium alcoholates. 2. Trans-esterification of esters of aromatic-acids. Organic Reactivity, 20 (1), 122−131.
1.1.
1982
Palm, V.; Hiob, R. (1982). Quantitative statistical interpretation of kinetic data in the gas-phase homolysis. 2. Results of data treatment in the coordinates of the isokinetic relationship. Organic Reactivity, 19 (1), 120−140.
1.1.
1981
Palm, V.; Hiob, R. (1981). Quantitative statistical interpretation of kinetic data in the gas-phase homolysis. 1. Modified calculation scheme for formation enthalpies in the gas-phase at 0-degrees-k. Organic Reactivity, 18 (3), 460−498.
1.1.
1981
Palm, VA.; Hiob, RJ. (1981). Structural effects in gas-phase homolysis. Organic Reactivity, 18 (1), 152−172.
3.4.
1981
Palm, V.; Hiob, R. (1981). Structural Effects in Gas Phase Homolysis. XII Mendeleev Congress, Baku, September 1981. Abstr. Pap. No 3. Moscow: Izdatelstvo Nauka, 28−29.
1.1.
1980
Nummert, V.; Palm, V. (1980). Study of solvent dependence of rho-degrees. 1. Statistical-data handling. Organic Reactivity, 17 (3), 292−312.
1.1.
1980
Nummert, V.; Palm, V. (1980). Study of solvent dependence of rho-degrees. 2. Results and discussion. Organic Reactivity, 17 (3), 331−351.
1.1.
1979
Korgesaar, A.; Danilov, I.; Palm, V. (1979). Study of reactivity of substituted bicyclo[2.2.2] octanes. 1. Formulation of the problem - on the methods of synthesis of disubstituted-derivatives of bicyclo[2.2.2]octane. Organic Reactivity, 16 (4), 521−528.
1.1.
1978
Karelson, M. M.; Palm, V. A. (1978). New Model of Electrical Conductivity of Aqueous Strong Electrolyte Solutions. Teoreticheskaya i Eksperimentalnaya Khimiya, 14, 781−787.
1.1.
1978
Linntam, AA.; Palm, VA. (1978). Study of possible applications of atomic orbital energy-model. 5. Statistical treatment of atomic spectral terms including electronic configurations up to 1s22s22p53d. Organic Reactivity, 15 (1), 93−123.
2.2.
1978
Palm, V.; Tenno, T.; Tamme, M.; Talvik, I.; Hiob, R.; Luuk, M.; Uudam, M.; Rodima, T. (1978). Tables of Rate and Equilibrium Constants of Heterolytic Organic Reactions. Moscow: VINITI.
1.1.
1977
Riikoja, J.; Timotheus, H.; Palm, V. (1977). Check of experimental-data on solvolysis kinetics of mannich-bases x1c6h4nhch2c(no2)2c6h4x2 used in parametrization of 4-factor polylinear equation with all gross-terms. Organic Reactivity, 14 (4), 507−526.
1.1.
1977
Yuriado, EK.; Palm, UV. (1977). Specific adsorption of ions on bismuth electrode from solutions in dimethyl-sulfoxide. 1. Soviet Electrochemistry, 13 (3), 389−392.
3.3.
1977
Palm, V. A.; Tenno, T. A.; Koppel, I. A.; Hiob, R. J.; Koppel, J. B.; Karelson, M. M. (1977). Tables of Rate and Equilibrium Constants of Heterolytic Reactions. VINITI.
1.1.
1976
Kozlov, V.; Ivanov, A.; Palm, V. (1976). Ratio of meta-isomers and para-isomers in equilibrium mixtures of disubstituted benzenes. Organic Reactivity, 13 (3), 315−327.
1.1.
1976
Nummert, VM.; Palm, VA. (1976). Study of electric-conductivity of o-coona-phenyl tosylate in aqueous-solutions of naoh. Organic Reactivity, 13 (1), 75−83.
1.1.
1976
Palm, VA. (1976). Study of possible applications of atomic orbital energy-model. 3. Estimation of screening and non-screening interelectronic interaction constants for 2nd shell orbitals. Organic Reactivity, 13 (1), 115−128.
1.1.
1976
Palm, VA. (1976). Study of possible applications of atomic orbital energy-model. 4. Energetically accurate basis for quantum-chemical calculations and possible realization procedure of latters. Organic Reactivity, 13 (1), 129−137.
3.3.
1975
Palm, V. A.; Tenno, T. A.; Koppel, I. A.; Hiob, R. J.; Rodima, T. A.; Karelson, M. M. (1975). Tables of Rate and Equilibrium Constants of Heterolytic Organic Reactions. Moscow: VINITI.
1.1.
1974
Karelson, M. M.; Palm, V.A. (1974). Hydrogen Bond Energy in Ice I Calculated by the Method of Electrostatic Interactions Between the Partial Charges. Organic Reactivity, 11, 667−678.
1.1.
1974
Karelson, M. M.; Palm, V. A.; Hiob, R.; Haldna, Ü. L. (1974). Ionization Mechanism of Strong Acids. Trichloroacetic, 2,4,6-Trinitrobenzoic, and Picric Acids in Aqueous Sulphuric Acid. Organic Reactivity, 11, 239−258.
1.1.
1974
Koppel, I.; Karelson, M.; Palm, V. (1974). Common Scale of Inductive Constants s * for Neutral and Charged Substituents. Organic Reactivity, 11, 101−120.
1.1.
1974
Palm, V. A.; Karelson, M. M. (1974). New Model for Solutions of Electrolytes. Organic Reactivity, 11, 263−268.
1.1.
1973
Palm, V.A.; Püssa, T.O.; Nummert, V.M.; Talvik, I.V. (1973). Polar Effects of Substituents in Alkylic Part. Organic Reactivity, 10 (1), 243−267.
1.1.
1973
Karelson, M. M.; Haldna, Ü. L.; Palm, V. A. (1973). Relationship between Equivalent Conductivity of Complexes of Proton with Oxonium Bases and Their Molecular Size. Organic Reactivity, 10, 163−174.
1.1.
1973
Karelson, M. M.; Palm, V. A.; Haldna, Ü. L. (1973). Differential-Conductometric Investigation of Hammett Indicator 2,4-Dinitroaniline. Organic Reactivity, 10, 323−331.
1.1.
1973
Karelson, M. M.; Palm, V. A.; Haldna, Ü. L. (1973). Investigation of Complexing of Nitrosubstituted Benzenes with Proton in Aqueous Solutions of Sulfuric Acid by Differential Conductometry. Organic Reactivity, 10, 307−322.
1.1.
1973
Koppel, I.; Karelson, M.; Palm, V. (1973). Demonstration of the Universality of the Constant a * of Inductive Interaction. Organic Reactivity, 10, 497−514.
1.1.
1973
Palm, V. A.; Nummert, V. M.; Püssa, T. O.; Karelson, M. M.; Koppel, I. A. (1973). On Electrostatic Contribution to Polar Effects of Charged Substituents and Nature of Primary Salt Effect. Organic Reactivity, 10, 223−242.
1.1.
1972
Püssa, T.O.; Palm, V.A. (1972). Acidic Hydrolysis of Benzoates. III. Organic Reactivity, 9 (4), 1209−1224.
1.1.
1972
Püssa, T.O.; Nummert, V.M.; Palm, V.A. (1972). Alkaline Hydrolysis of Alkyl Benzoates in Water. II. Organic Reactivity, 9 (3), 871−889.
1.1.
1972
Püssa, T.O.; Nummert, V.M.; Palm, V.A. (1972). Alkaline Hydrolysis of Substituted Phenyl Benzoates. I. Organic Reactivity, 9 (3), 697−728.
1.1.
1972
Karelson, M.; Palm, V. A.; Haldna, Ü. L. (1972). Experimental Proof of the Constancy of Hydrogen Ion Equivalent Conductivity in System H2SO4 - H2O and the Ground of Differential Conductometric Method of Investigation of Protolytic Equilibria. Organic Reactivity, 9, 831−846.
1.1.
1971
Maremäe, V.M.; Püssa, T.O.; Palm, V.A. (1971). Influence of Ionic Strength of Medium on Hydrolysis Rate of o-, m- and p-N(CH3)3+ - Phenyl p-Toluene Sulfonates. Organic Reactivity, 8 (1), 127−151.
1.1.
1967
Neimyshe, AA.; Palm, VA.; Semin, GK.; Loshadki, NA.; Knunyant, IL. (1967). Nucleophilic substitution in derivatives of phosphorus acids. 2. Relation between structure of phosphorus-containing compounds and reactivity - application of correlation equations. Journal of General Chemistry USSR, 37 (10), 2140.
1.1.
1962
Palm, VA.; Vizgert, RV. (1962). Correlation of rate constants in alkaline hydrolysis of aromatic sulfoacid esters, as dependent on structur of these compounds. Doklady Akademii Nauk SSSR, 142 (5), 1091.
1.1.
1962
Palm, VA.; Khaldna, YL.; Talnik, AI.; Mei, AE. (1962). Protonization of carbonyl compounds and the mechanism of the acid hydrolysis of esters. Zhurnal Fizicheskoi Khimii, 36 (11), 2499−2501.
1.1.
1961
Palm, VA. (1961). Structure and reactivity of organic compounds (quantitative laws). Russian Chemical Reviews = Uspekhi Khimiy, 30 (9), 471−498.
1.1.
1961
Kozlova, KR.; Palm, VA. (1961). Synthesis of tetraphenylboronsodium in a tetrahydrofuran solution. Zhurnal Obshchei Khimii, 31 (9), 2922.
1.1.
1960
Khaldna, IL.; Palm, VA. (1960). The reduction of basicities to a single standard state - an investigation of the basicity of acetone. Doklady Akademii Nauk SSSR, 135 (3), 667−670.
1.1.
1959
Talvik, AJ.; Palm, VA. (1959). Reactive ability of anions of some carboxylic acids in the acid-catalysed enolization of acetone. Doklady Akademii Nauk SSSR, 129 (6), 1349−1352.
1.1.
1959
Talvik, AI.; Palm, VA. (1959). Studies on the kinetics and mechanism of acid hydrolysis of ethyl acetate. Zhurnal Fizicheskoi Khimii, 33 (6), 1214−1220.
27.11.2018

Viktor Palm

https://etis.ee/CV/Viktor_Palm/eng
17.09.1926
737 5262
viktor.palm@ut.ee

Career

Institutions and positions
1952 - 1964 - Department of Organic Chemistry, Tartu University, Teacher, Docent
1964-1992 - Docent, Professor, Head of Department of Organic Chemistry
1992-2005 - Institute Of Chem. Physics, Tartu University, Professor Emeritus, Senior Research Fellow
01.07.2006–31.07.2007   
University of Tartu, Faculty of Physics and Chemistry, Institute of Chemical Physics, Research Fellow extraordinarius (0,25)
 
 
Education
Higher, Leningrad State University, 1952
 
 
R&D related managerial and administrative work
-

Qualifications

Academic degrees
Viktor Palm, Doctor's Degree, 1966, (sup) -, Quantitative Investigations on Organic Reactivity, Instit. of Elementorg. Chem. Ac. Sci. USSR.
 
 
Honours & awards
1997, Viktor Palm, National Science Prize
0, Viktor Palm, Member of the Estonian Acad. of. Sci. from 1978,
 
 
Additional information
D. Sci. (Chemistry), Instit. of Elementorg. Chem. Ac. Sci. USSR, 1966

Supervised dissertations

Publications

Category
Year
Publication
 
1.2.
2006
Palm, V.; Palm, N.; Tenno, T. (2006). Computerized database and software for retrieval, processing and prognosis of rate and equilibrium constants of chemical reactions. Proceedings of the Estonian Academy of Sciences. Chemistry, 55 (1), 3−13.
1.1.
2004
Palm, V.; Palm, N.; Tenno, T. (2004). Modification of data processing and interpretation of results related to the use of multiparameter correlation analysis: introduction of additional characteristics and criterias. Part 1 - Application to the treatment of solvent effects. Journal of Physical Organic Chemistry, 17 (10), 876−889.
5.1.
2004
Palm, V.; Kiho, J.; Jalas, A.; Tenno, T.; Palm, N. (2004). Computerized Database on Chemical Reactivity (Rate and Equilibrium Constants) and Concerted Software for Retrieval, Processing, and Prognosis of Data. International Conference on Education and Information Systems: Technologies and Applications, vol, 2, Proceedings: International Conference on Education and Information Systems (EISTA '04); Orlando, USA; 21-25 July, 2004. Orlando, USA, 190−195.
5.2.
2004
Palm, V.; Tenno, T.; Palm, N. (2004). Averaged Values and the Problem of Generality for Substituent Constants. The Tenth International Conference on Correlation Analyis in Chemistry (CAIC, X): The Tenth International Conference on Correlation Analyis in Chemistry; Busan, Korea; 2004.
1.1.
2001
Palm, N.; Palm, V. (2001). Verification of the Modified Approach to Solvation Effects on The Basis of Extended Data Set: III. Results of Statistical Data Treatment for Particular Processes. Russian Journal of Organic Chemistry, 37 (7), 935−939.
1.2.
2001
Jalas, A.; Palm, V.; Tenno, T. (2001). A Computerized Storage and Retrieval System of pKa Values of Hydrogen Acids. Proceedings of the Estonian Academy of Sciences. Chemistry, 50 (3), 186−192.
3.1.
2001
Palm, V. (2001). Some fundamental criteria of the scientific method and the internal structure of science. In: Vihalemm, R. (Ed.). Estonian studies in the history and philosophy of science (91−110). . Dordrecht/Boston/London: Kluwer Academic Publishers. (Boston studies in the philosophy of science; 219).
3.3.
2001
Palm, V.; Jalas, A.; Tenno, T. (2001). PKa Database. Dissociation of Hydrogen Acids (http:/mega.chem.ut.ee/tktool/teadus/pkdb). 1.
1.1.
2000
Palm, N.; Palm, V. (2000). Verification of modified approach to solvation effects based on extended set of data series II: Procedure and verification results of averaged statistical significance of solvent constants scales. Russian Journal of Organic Chemistry, 36 (8), 1075−1104.
1.2.
1997
Palm, V.; Palm, N. (1997). Check of a Modified Approach to Solvent Effects by Processing of an Extended Set of Solvent-Dependent Data Series. 1. Test of an Earlier Defined Set of Nine Solvent Parameters. Organic Reactivity, 31 (104), 141−158.
1.3.
1997
Palm, V.; Jalas, A.; Kiho, J.; Tenno, T. (1997). A Computerised System for the Storage, Processing and Prognostication of Data with Orientation Toward the Use of Correlation Equations. Organic Reactivity, 31 (1), 111−133.
1.3.
1997
Jalas, A.; Kiho, J.; Palm, V.; Tenno, T. (1997). Data Structure and Menu-based Access of the Rate and Equilibrium Constants of Heterolytic Organic Reactions Database. Organic Reactivity, 31 (1), 135−140.
1.2.
1996
Nummert, V.; Piirsalu, M.; Palm, V. (1996). Kinetic Study of Hydrolysis of Benzoates. XIX. Influence of Temperature on Ortho Effect for Water Solution. Isokinetic Dependence in the Case of Additional Ortho Induction Effect. Organic Reactivity, 30, 85−94.
1.1.
1993
Hiob, R.; Palm, V. (1993). Structural and Temperature Effects in the Gas Phase Hydrogen Abstraction Reactions from Compounds with General Structure R-H. 2. Abstraction by Variable Free Radicals. Organic Reactivity, 28, 119−124.
1.1.
1993
Palm, V.; Palm, N. (1993). On the Total Number and List of Parameter Scales Significant for General Quantitative Description of Solvent Effects. Organic Reactivity, 28, 125−152.
1.1.
1993
Hiob, R.; Palm, V. (1993). Structural and Temperature Effects in the Gas Phase Hydrogen Abstraction Reactions from Compounds with General Structure R-H. Abstraction by Hydrogen Atom. Organic Reactivity, 28, 110−118.
1.2.
1993
Nummert, V.; Piirsalu, M.; Palm, V. (1993). Kinetic Study of Alkaline Hydrolysis of Substituted Phenyl Tosylates. XXI. Influence of Solvent on Ortho Effect. Organic Reactivity, 28, 82−87.
1.2.
1993
Hiob, R.; Palm, V. (1993). Structural and Temperature Effects in the Gas Phase Hydrogen Abstraction Reactions from Compounds with General Structure R-H. 1. Abstraction by Hydrogen Atom. Organic Reactivity, 28, 110−118.
1.1.
1990
Palm, V. (1990). Computer-managed automatic data-retrieval and prognosis system for rate and equilibrium-constants of organic-reactions. Journal of Chemical Information and Computer Sciences, 30 (4), 409−412.
1.1.
1990
Nummert, VM.; Piirsalu, MV.; Palm, VA. (1990). Kinetic-study of alkaline-hydrolysis of substituted phenyl tosylates. 18. Results of kinetic measurements of o-substituted tosylates in 80-percent aqueous dimethylsulfoxide. Organic Reactivity, 27, 99−127.
1.1.
1987
Tuulmets, A.; Horak, M.; Hansen, E.; Palm, V. (1987). Some structure-reactivity relationships for alkylbromides in the grignard reaction. Organic Reactivity, 24 (4), 412−424.
1.1.
1986
Palm, V.; Hiob, R.J. (1986). Quantitative Statistical Interpretation of Kinetic Data in the Gas-Phase Homolysis .8. Program for Automatic Computational Estimation of Rate Constants of Gas-Phase Homolysis and Heats of Formation of Covalent Compounds. Organic Reactivity, 23 (4), 412−439.
1.1.
1986
Palm, VA.; Hiob, RJ. (1986). Quantitative statistical interpretation of kinetic data in the gas-phase homolysis. 8. Program for automatic computational estimation of rate constants of gas-phase homolysis and heats of formation of covalent compounds. Organic Reactivity, 23 (4), 412−439.
1.1.
1986
Sild, VA.; Palm, VA. (1986). Realization of the general algorithm of the solution of direct problems for homogeneous equilibrium-kinetic mechanistic schemes. Organic Reactivity, 23 (4), 482−506.
1.1.
1985
Koppel, IA.; Molder, UH.; Palm, VA. (1985). Abinitio SCF LCAO MO calculations of molecules. 4. Proton affinities - comparison with experiment. Organic Reactivity, 22 (1), 3−45.
1.1.
1985
Palm, N.; Palm, V. (1985). Determination of the kinetic equilibrium parameters of the reaction of triphenylaluminum with benzophenone. Organic Reactivity, 22 (2), 131−141.
1.1.
1985
Matveev, AA.; Piskunova, ZP.; Palm, VA. (1985). Factors effecting rate of menshutkin reaction. 1. Effect of amine structure. Organic Reactivity, 22 (1), 110−118.
1.1.
1985
Matveev, AA.; Piskunova, ZP.; Palm, VA. (1985). Factors effecting the rate of menshutkin reaction. 2. Interdependence of reagents structure effects. Organic Reactivity, 22 (2), 153−161.
1.1.
1985
Nummert, V.; Eek, M.; Palm, V. (1985). Kinetic-study of alkaline-hydrolysis of substituted phenyl tosylates. 14. Discussion of results of kinetic measurements in 80-percent aqueous dimethylsulfoxide. Organic Reactivity, 22 (3), 263−294.
1.1.
1984
Leinbock, RA.; Palm, VA. (1984). Nonlinear parametrization of equations for atomic spectral terms. 2. Data-processing applying the minimization of relative standard-deviation in the equation with a reduced number of parameters. Organic Reactivity, 21 (2), 127−143.
1.1.
1984
Juriado, TJ.; Palm, VA. (1984). Program package for computer-storage and automatic search of correlation equations and for calculation of rate and equilibrium-constants. 1. Digital coding system of equations of chemical-reactions. Organic Reactivity, 21 (3), 255−284.
1.1.
1983
Leinbock, RA.; Palm, VA. (1983). Nonlinear parametrization of equations for atomic spectral terms. 1. Specification of general character of dependence on orbital-orbital shielding constants. Organic Reactivity, 20 (3), 373−396.
1.1.
1983
Hiob, R.; Palm, V. (1983). Quantitative statistical interpretation of kinetic data in the gas-phase homolysis. 3. Calculation of conventional formation enthalpies of free-radicals in the approximation of constant effective mean-value of log a0=14.64. Organic Reactivity, 20 (2), 151−202.
1.1.
1983
Hiob, R.; Palm, V. (1983). Quantitative statistical interpretation of kinetic data in the gas-phase homolysis. 4. Calculation of conventional formation enthalpies of free-radicals based on experimental activation-energies, isokinetic and isoentropic models. Organic Reactivity, 20 (2), 257−274.
1.1.
1983
Palm, VA.; Hiob, RJ. (1983). Quantitative statistical interpretation of kinetic data in the gas-phase homolysis. 5. Correlation of substituent effects on conventional formation enthalpies of substituted methyl radicals proceeding from isoentropic and isokinetic models. Organic Reactivity, 20 (3), 321−354.
1.1.
1983
Hiob, RJ.; Palm, VA. (1983). Quantitative statistical interpretation of kinetic data in the gas-phase homolysis. 6. Attempt of simultaneous estimation of entropy and enthalpy contributions in free-energy of activation. Organic Reactivity, 20 (3), 405−443.
1.1.
1983
Uri, A.; Tuulmets, A.; Palm, V. (1983). Trans-esterification of esters of carboxylic-acids by titanium alcoholates. 2. Trans-esterification of esters of aromatic-acids. Organic Reactivity, 20 (1), 122−131.
1.1.
1982
Palm, V.; Hiob, R. (1982). Quantitative statistical interpretation of kinetic data in the gas-phase homolysis. 2. Results of data treatment in the coordinates of the isokinetic relationship. Organic Reactivity, 19 (1), 120−140.
1.1.
1981
Palm, V.; Hiob, R. (1981). Quantitative statistical interpretation of kinetic data in the gas-phase homolysis. 1. Modified calculation scheme for formation enthalpies in the gas-phase at 0-degrees-k. Organic Reactivity, 18 (3), 460−498.
1.1.
1981
Palm, VA.; Hiob, RJ. (1981). Structural effects in gas-phase homolysis. Organic Reactivity, 18 (1), 152−172.
3.4.
1981
Palm, V.; Hiob, R. (1981). Structural Effects in Gas Phase Homolysis. XII Mendeleev Congress, Baku, September 1981. Abstr. Pap. No 3. Moscow: Izdatelstvo Nauka, 28−29.
1.1.
1980
Nummert, V.; Palm, V. (1980). Study of solvent dependence of rho-degrees. 1. Statistical-data handling. Organic Reactivity, 17 (3), 292−312.
1.1.
1980
Nummert, V.; Palm, V. (1980). Study of solvent dependence of rho-degrees. 2. Results and discussion. Organic Reactivity, 17 (3), 331−351.
1.1.
1979
Korgesaar, A.; Danilov, I.; Palm, V. (1979). Study of reactivity of substituted bicyclo[2.2.2] octanes. 1. Formulation of the problem - on the methods of synthesis of disubstituted-derivatives of bicyclo[2.2.2]octane. Organic Reactivity, 16 (4), 521−528.
1.1.
1978
Karelson, M. M.; Palm, V. A. (1978). New Model of Electrical Conductivity of Aqueous Strong Electrolyte Solutions. Teoreticheskaya i Eksperimentalnaya Khimiya, 14, 781−787.
1.1.
1978
Linntam, AA.; Palm, VA. (1978). Study of possible applications of atomic orbital energy-model. 5. Statistical treatment of atomic spectral terms including electronic configurations up to 1s22s22p53d. Organic Reactivity, 15 (1), 93−123.
2.2.
1978
Palm, V.; Tenno, T.; Tamme, M.; Talvik, I.; Hiob, R.; Luuk, M.; Uudam, M.; Rodima, T. (1978). Tables of Rate and Equilibrium Constants of Heterolytic Organic Reactions. Moscow: VINITI.
1.1.
1977
Riikoja, J.; Timotheus, H.; Palm, V. (1977). Check of experimental-data on solvolysis kinetics of mannich-bases x1c6h4nhch2c(no2)2c6h4x2 used in parametrization of 4-factor polylinear equation with all gross-terms. Organic Reactivity, 14 (4), 507−526.
1.1.
1977
Yuriado, EK.; Palm, UV. (1977). Specific adsorption of ions on bismuth electrode from solutions in dimethyl-sulfoxide. 1. Soviet Electrochemistry, 13 (3), 389−392.
3.3.
1977
Palm, V. A.; Tenno, T. A.; Koppel, I. A.; Hiob, R. J.; Koppel, J. B.; Karelson, M. M. (1977). Tables of Rate and Equilibrium Constants of Heterolytic Reactions. VINITI.
1.1.
1976
Kozlov, V.; Ivanov, A.; Palm, V. (1976). Ratio of meta-isomers and para-isomers in equilibrium mixtures of disubstituted benzenes. Organic Reactivity, 13 (3), 315−327.
1.1.
1976
Nummert, VM.; Palm, VA. (1976). Study of electric-conductivity of o-coona-phenyl tosylate in aqueous-solutions of naoh. Organic Reactivity, 13 (1), 75−83.
1.1.
1976
Palm, VA. (1976). Study of possible applications of atomic orbital energy-model. 3. Estimation of screening and non-screening interelectronic interaction constants for 2nd shell orbitals. Organic Reactivity, 13 (1), 115−128.
1.1.
1976
Palm, VA. (1976). Study of possible applications of atomic orbital energy-model. 4. Energetically accurate basis for quantum-chemical calculations and possible realization procedure of latters. Organic Reactivity, 13 (1), 129−137.
3.3.
1975
Palm, V. A.; Tenno, T. A.; Koppel, I. A.; Hiob, R. J.; Rodima, T. A.; Karelson, M. M. (1975). Tables of Rate and Equilibrium Constants of Heterolytic Organic Reactions. Moscow: VINITI.
1.1.
1974
Karelson, M. M.; Palm, V.A. (1974). Hydrogen Bond Energy in Ice I Calculated by the Method of Electrostatic Interactions Between the Partial Charges. Organic Reactivity, 11, 667−678.
1.1.
1974
Karelson, M. M.; Palm, V. A.; Hiob, R.; Haldna, Ü. L. (1974). Ionization Mechanism of Strong Acids. Trichloroacetic, 2,4,6-Trinitrobenzoic, and Picric Acids in Aqueous Sulphuric Acid. Organic Reactivity, 11, 239−258.
1.1.
1974
Koppel, I.; Karelson, M.; Palm, V. (1974). Common Scale of Inductive Constants s * for Neutral and Charged Substituents. Organic Reactivity, 11, 101−120.
1.1.
1974
Palm, V. A.; Karelson, M. M. (1974). New Model for Solutions of Electrolytes. Organic Reactivity, 11, 263−268.
1.1.
1973
Palm, V.A.; Püssa, T.O.; Nummert, V.M.; Talvik, I.V. (1973). Polar Effects of Substituents in Alkylic Part. Organic Reactivity, 10 (1), 243−267.
1.1.
1973
Karelson, M. M.; Haldna, Ü. L.; Palm, V. A. (1973). Relationship between Equivalent Conductivity of Complexes of Proton with Oxonium Bases and Their Molecular Size. Organic Reactivity, 10, 163−174.
1.1.
1973
Karelson, M. M.; Palm, V. A.; Haldna, Ü. L. (1973). Differential-Conductometric Investigation of Hammett Indicator 2,4-Dinitroaniline. Organic Reactivity, 10, 323−331.
1.1.
1973
Karelson, M. M.; Palm, V. A.; Haldna, Ü. L. (1973). Investigation of Complexing of Nitrosubstituted Benzenes with Proton in Aqueous Solutions of Sulfuric Acid by Differential Conductometry. Organic Reactivity, 10, 307−322.
1.1.
1973
Koppel, I.; Karelson, M.; Palm, V. (1973). Demonstration of the Universality of the Constant a * of Inductive Interaction. Organic Reactivity, 10, 497−514.
1.1.
1973
Palm, V. A.; Nummert, V. M.; Püssa, T. O.; Karelson, M. M.; Koppel, I. A. (1973). On Electrostatic Contribution to Polar Effects of Charged Substituents and Nature of Primary Salt Effect. Organic Reactivity, 10, 223−242.
1.1.
1972
Püssa, T.O.; Palm, V.A. (1972). Acidic Hydrolysis of Benzoates. III. Organic Reactivity, 9 (4), 1209−1224.
1.1.
1972
Püssa, T.O.; Nummert, V.M.; Palm, V.A. (1972). Alkaline Hydrolysis of Alkyl Benzoates in Water. II. Organic Reactivity, 9 (3), 871−889.
1.1.
1972
Püssa, T.O.; Nummert, V.M.; Palm, V.A. (1972). Alkaline Hydrolysis of Substituted Phenyl Benzoates. I. Organic Reactivity, 9 (3), 697−728.
1.1.
1972
Karelson, M.; Palm, V. A.; Haldna, Ü. L. (1972). Experimental Proof of the Constancy of Hydrogen Ion Equivalent Conductivity in System H2SO4 - H2O and the Ground of Differential Conductometric Method of Investigation of Protolytic Equilibria. Organic Reactivity, 9, 831−846.
1.1.
1971
Maremäe, V.M.; Püssa, T.O.; Palm, V.A. (1971). Influence of Ionic Strength of Medium on Hydrolysis Rate of o-, m- and p-N(CH3)3+ - Phenyl p-Toluene Sulfonates. Organic Reactivity, 8 (1), 127−151.
1.1.
1967
Neimyshe, AA.; Palm, VA.; Semin, GK.; Loshadki, NA.; Knunyant, IL. (1967). Nucleophilic substitution in derivatives of phosphorus acids. 2. Relation between structure of phosphorus-containing compounds and reactivity - application of correlation equations. Journal of General Chemistry USSR, 37 (10), 2140.
1.1.
1962
Palm, VA.; Vizgert, RV. (1962). Correlation of rate constants in alkaline hydrolysis of aromatic sulfoacid esters, as dependent on structur of these compounds. Doklady Akademii Nauk SSSR, 142 (5), 1091.
1.1.
1962
Palm, VA.; Khaldna, YL.; Talnik, AI.; Mei, AE. (1962). Protonization of carbonyl compounds and the mechanism of the acid hydrolysis of esters. Zhurnal Fizicheskoi Khimii, 36 (11), 2499−2501.
1.1.
1961
Palm, VA. (1961). Structure and reactivity of organic compounds (quantitative laws). Russian Chemical Reviews = Uspekhi Khimiy, 30 (9), 471−498.
1.1.
1961
Kozlova, KR.; Palm, VA. (1961). Synthesis of tetraphenylboronsodium in a tetrahydrofuran solution. Zhurnal Obshchei Khimii, 31 (9), 2922.
1.1.
1960
Khaldna, IL.; Palm, VA. (1960). The reduction of basicities to a single standard state - an investigation of the basicity of acetone. Doklady Akademii Nauk SSSR, 135 (3), 667−670.
1.1.
1959
Talvik, AJ.; Palm, VA. (1959). Reactive ability of anions of some carboxylic acids in the acid-catalysed enolization of acetone. Doklady Akademii Nauk SSSR, 129 (6), 1349−1352.
1.1.
1959
Talvik, AI.; Palm, VA. (1959). Studies on the kinetics and mechanism of acid hydrolysis of ethyl acetate. Zhurnal Fizicheskoi Khimii, 33 (6), 1214−1220.
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ProgrammLiikNumberNimiProjekti algusProjekti lõppVastutav täitjaAsutusFinantseerijapoolne rahastamine
SFSF0182552s03Keemiliste ühendite reaktsioonivõime ja omaduste eksperimentaalne ja teoreetiline uurimine.01.01.200331.12.2007Ilmar KoppelTartu Ülikool, Füüsika-keemiateaduskond846 906,04 EUR
ETFETF6476Substituendikonstantide keskmistatud väärtuste leidmine lähtudes võimalikult suurtest ja mitmekesistest andmeseeriate komplektidest.01.01.200531.12.2008Natalia PalmTartu Ülikool, Füüsika-keemiateaduskond; Tartu Ülikool, Loodus- ja tehnoloogiateaduskond19 747,34 EUR
SFSF0180089s08Superhapete ja superaluste keemia ja selle rakendused01.01.200831.12.2013Ilmar KoppelTartu Ülikool, Loodus- ja tehnoloogiateaduskond, Tartu Ülikooli Keemia Instituut1 278 255,77 EUR